|Captain Tsubasa 5: Hasha no Shogo Campione|
|Box cover & back cover|
|Composer(s)||Hiroshi Miyazaki, Chinatsu Okayasu|
- Juan Diaz (ディアス): playmaker and leader of Albicelestes, loosely based on Diego Maradona; Díaz has five different shot techniques and a combination technique with teammate Alan Pascal, the Argentina Combi.
- Arantes (アランチス): based on football legend Pelé; he plays for Canarinho Stars - the strongest team in the game, which consists of players inspired by classic Brazilian stars: Garrincha, Gilmar, Rivelino or Zico; he does not possess any special techniques, however his individual attributes are extremely high.
- João Aragones (ジョアン): coach of Campione and former tutor of Roberto Hongo; taught his best players (Nitta, Alcion and Signori) the unique technique - Geijutsu Teki Dribble.
- Signori (シニョーリ): one of the most important characters in this instalment of the game; arrogant Brazilian midfielder/forward with effective dribble and trademark Axel Spin Shot, Signori plays for Seleção and Parma. Signori featured in the game's manual.
- Schneider (カール・ハインツ・シュナイダー): world-class forward with total of 8 special techniques, including potent Neofire Shot; Schneider plays for FC Bayern Munich and is one of Tsubasa's greatest rivals.
- Stratto (ストラット): star player of AC Milan and Italy, known from Captain Tsubasa 4; he is able to beat most of goalkeepers with his powerful Megaton Shot.
- Kusta (クスタ): arguably the best defender in the game, he plays for Malaysia and Campione; hard to beat due to his special defensive techniques: block, charge and tackle.
- Furia (フーリア): skilful midfielder of AC Milan, inspired by Dutch Ballon d'Or winner Ruud Gullit.
- Van Berg (ファン・ベルグ): based on Marco van Basten; possess very good shot technique and heading ability; despite his great skills, he is only substitute at Milan. At the time of the release of the game, Van Basten was seriously injured, which resulted in his early retirement.
- Kanu (カヌー): player with decent technique, based on Nwankwo Kanu from 1993 FIFA U-17 World Championship winning team; characters resembling other members of that squad: Wilson Oruma and Celestine Babayaro are also present in the game.